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DC Field | Value | Language |
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dc.contributor.author | Costa, M.D.P. De | - |
dc.contributor.author | Pincock, J. | - |
dc.date.accessioned | 2011-10-04T09:47:18Z | - |
dc.date.available | 2011-10-04T09:47:18Z | - |
dc.date.issued | 2002 | - |
dc.identifier.uri | http://archive.cmb.ac.lk:8080/xmlui/handle/70130/125 | - |
dc.description.abstract | Irradiation in acetonitrile of any one of the six isomers of dimethylbenzotrifluoride 8 resulted in efficient photoisomerization to the others. The dominant processes in these phototransposition reactions divides the isomers into two triads. The first consists of 8-2,6 (2,6-dimethylbenzotrifluoride), 8-2,3, and 8-3,4; the second consists of 8-3,5, 8-2,4, and 8-2,5. Moreover, irradiation of 2,6-dideuterio-4-methylbenzotrifluoride 5-d2 resulted in formation of 5,6-dideuterio-3-methylbenzotrifluoride 6-d2. These observations demonstrate that it is the trifluoromethyl-substituted carbon that is the migratory one in these reactions. | en_US |
dc.language.iso | en | en_US |
dc.subject | Phototransposition Reactions | en_US |
dc.subject | Role of Trifluoromethyl | en_US |
dc.title | Phototransposition Reactions of Methyl-Substituted Benzotrifluorides: Proof of the Role of Trifluoromethyl-Substituted Carbon | en_US |
dc.type | Research abstract | en_US |
Appears in Collections: | Department of Chemistry |
Files in This Item:
File | Description | Size | Format | |
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Organic Chemistry_abstract[1].docx Dayal D Costa.doc | 23.5 kB | Microsoft Word | View/Open |
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