Please use this identifier to cite or link to this item: http://archive.cmb.ac.lk:8080/xmlui/handle/70130/125
Full metadata record
DC FieldValueLanguage
dc.contributor.authorCosta, M.D.P. De-
dc.contributor.authorPincock, J.-
dc.date.accessioned2011-10-04T09:47:18Z-
dc.date.available2011-10-04T09:47:18Z-
dc.date.issued2002-
dc.identifier.urihttp://archive.cmb.ac.lk:8080/xmlui/handle/70130/125-
dc.description.abstractIrradiation in acetonitrile of any one of the six isomers of dimethylbenzotrifluoride 8 resulted in efficient photoisomerization to the others. The dominant processes in these phototransposition reactions divides the isomers into two triads. The first consists of 8-2,6 (2,6-dimethylbenzotrifluoride), 8-2,3, and 8-3,4; the second consists of 8-3,5, 8-2,4, and 8-2,5. Moreover, irradiation of 2,6-dideuterio-4-methylbenzotrifluoride 5-d2 resulted in formation of 5,6-dideuterio-3-methylbenzotrifluoride 6-d2. These observations demonstrate that it is the trifluoromethyl-substituted carbon that is the migratory one in these reactions.en_US
dc.language.isoenen_US
dc.subjectPhototransposition Reactionsen_US
dc.subjectRole of Trifluoromethylen_US
dc.titlePhototransposition Reactions of Methyl-Substituted Benzotrifluorides: Proof of the Role of Trifluoromethyl-Substituted Carbonen_US
dc.typeResearch abstracten_US
Appears in Collections:Department of Chemistry

Files in This Item:
File Description SizeFormat 
Organic Chemistry_abstract[1].docx Dayal D Costa.doc23.5 kBMicrosoft WordView/Open


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.